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Cyanide Bath For Tool Steels
All high-carbon tool steels are heated in a cyanide bath. Wi...

Connecting Rods
The material used for all connecting rods on the Liberty engi...

Sulphur
Sulphur is another impurity and high sulphur is even a greate...

Open Hearth Process
The open hearth furnace consists of a big brick room with a l...

Impact Tests
Impact tests are of considerable importance as an indication ...

Pyrometers
Armor plate makers sometimes use the copper ball or Siemens' ...

High-chromium Or Rust-proof Steel
High-chromium, or what is called stainless steel containing f...

Silicon
Silicon prevents, to a large extent, defects such as gas bubb...

Manganese
MANGANESE is a metal much like iron. Its chemical symbol is M...

Pyrometers For Molten Metal
Pyrometers for molten metal are connected to portable thermoc...

Steel Before The 1850's
In spite of a rapid increase in the use of machines and the ...

Introduction Of Carbon
The matter to which these notes are primarily directed is the...

Non-shrinking Oil-hardening Steels
Certain steels have a very low rate of expansion and contract...

Application To The Automotive Industry
The information given on the various parts of the Liberty eng...

Annealing Method
Forgings which are too hard to machine are put in pots with ...

Steel Can Be Worked Cold
As noted above, steel can be worked cold, as in the case of ...

Heating Of Manganese Steel
Another form of heat-treating furnace is that which is used ...

William Kelly's Air-boiling Process
An account of Bessemer's address to the British Association w...

Hints For Tool Steel Users
Do not hesitate to ask for information from the maker as to t...

Gas Consumption For Carburizing
Although the advantages offered by the gas-fired furnace for ...



Rate Of Absorption






Category: CASE-HARDENING OR SURFACE-CARBURIZING

According to Guillet, the absorption of carbon is favored by those
special elements which exist as double carbides in steel. For example,
manganese exists as manganese carbide in combination with the iron
carbide. The elements that favor the absorption of carbon are:
manganese, tungsten, chromium and molybdenum those opposing it,
nickel, silicon, and aluminum. Guillet has worked out the effect
of the different elements on the rate of penetration in comparison
with steel that absorbed carbon at a given temperature, at an average
rate of 0.035 in. per hour.

His tables show that the following elements require an increased
time of exposure to the carburizing material in order to obtain
the same depth of penetration as with simple steel:

When steel contains Increased time of exposure
2.0 per cent nickel 28 per cent
7.0 per cent nickel 30 per cent
1.0 per cent titanium 12 per cent
2.0 per cent titanium 28 per cent
0.5 per cent silicon 50 per cent
1.0 per cent silicon 80 per cent
2.0 per cent silicon 122 per cent
5.0 per cent silicon No penetration
1.0 per cent aluminum 122 per cent
2.0 per cent aluminum 350 per cent

The following elements seem to assist the rate of penetration of
carbon, and the carburizing time may therefore be reduced as follows:

When steel contains Decreased time of exposure
0.5 per cent manganese 18 per cent
1.0 per cent manganese 25 per cent
1.0 per cent chromium 10 per cent
2.0 per cent chromium 18 per cent
0.5 per cent tungsten 0
1.0 per cent tungsten 0
2.0 per cent tungsten 25 per cent
1.0 per cent molybdenum 0
2.0 per cent molybdenum 18 per cent

The temperature at which carburization is accomplished is a very
important factor. Hence the necessity for a reliable pyrometer,
located so as to give the temperature just below the tops of the
pots. It must be remembered, however, that the pyrometer gives
the temperature of only one spot, and is therefore only an aid to
the operator, who must use his eyes for successful results.

The carbon content of the case generally is governed by the temperature
of the carburization. It generally proves advisable to have the
case contain between 0.90 per cent and 1.10 carbon; more carbon
than this gives rise to excess free cementite or carbide of iron,
which is detrimental, causing the case to be brittle and apt to chip.

T. G. Selleck gives a very useful table of temperatures and the
relative carbon contents of the case of steels carburized between
4 and 6 hrs. using a good charcoal carburizer. This data is as
follows:

TABLE 15.--CARBON CONTENT OBTAINED AT VARIOUS TEMPERATURES

At 1,500 deg.F., the surface carbon content will be 0.90 per cent
At 1,600 deg.F., the surface carbon content will be 1.00 per cent
At 1,650 deg.F., the surface carbon content will be 1.10 per cent
At 1,700 deg.F., the surface carbon content will be 1.25 per cent
At 1,750 deg.F., the surface carbon content will be 1.40 per cent
At 1,800 deg.F., the surface carbon content will be 1.75 per cent

To this very valuable table, it seems best to add the following
data, which we have used for a number of years. We do not know
the name of its author, but it has proved very valuable, and seems
to complete the above information. The table is self-explanatory,
giving depth of penetration of the carbon of the case at different
temperatures for different lengths of time:

---------------------------------------------------------
Temperature
Penetration -----------------------------
1,550 1,650 1,800
------------------------------------------------------
Penetration after 1/2 hr. 0.008 0.012 0.030
Penetration after 1 hr. 0.018 0.026 0.045
Penetration after 2 hr. 0.035 0.048 0.060
Penetration after 3 hr. 0.045 0.055 0.075
Penetration after 4 hr. 0.052 0.061 0.092
Penetration after 6 hr. 0.056 0.075 0.110
Penetration after 8 hr. 0.062 0.083 0.130
---------------------------------------------------------

From the tables given, we may calculate with a fair degree of certainty
the amount of carbon in the case, and its penetration. These figures
vary widely with different carburizers, and as pointed out immediately
above, with different alloy steels.





Next: Carburizing Material

Previous: Surface Carburizing



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